Copper(II) Complexes Containing 3-n-Nonylcatechol: Preparation and Ligand Oxidation
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چکیده
Copper, Dioxygenase, Urushiol Model, Catechol Ternary copper(II) complexes containing the dianion of 3-n-nonylcatechol and a number of bidentate nitrogen containing counter ligands have been prepared and characterized. It has been demonstrated that, in the presence of oxygen, the catecholato ligand undergoes intradiol ring cleavage in a fashion similar to that carried out by intradiol aromatic dioxygenases. The 3-n-nonylcatecholato ligand was chosen as an analog for the naturally occuring 3-pentadecylcatechols or "urushiols" which are the active allergens in plants such as poison ivy.
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تاریخ انتشار 2012